Cover image for Reactive intermediate chemistry
Başlık:
Reactive intermediate chemistry
Yazar:
Moss, Robert A.
ISBN:
9780471233244
Yayım Bilgisi:
Hoboken, N.J. : Wiley-Interscience, c2004.
Fiziksel Tanım:
viii, 1072 p. : ill. ; 25 cm.
Contents:
Carbocations / Crossing the borderline between SN1 and SN2 nucleophilic substitution at aliphatic carbon / Carbanions / Radicals / Non-kekulâe molecules as reactive intermediates / Organic radical ions / Singlet carbenes / Stable singlet carbenes / Triplet carbenes / Atomic carbon / Nitrenes / Synthetic carbene and nitrene chemistry / Nitrenium ions / Silylenes (and germylenes, stannylenes, plumbylenes) / Strained hydrocarbons: structures, stability, and reactivity / Arynes / Matrix isolation / Nanosecond laser flash photolysis: a tool for physical organic chemistry / The picosecond realm / Reactions on the femtosecond time scale / Potential energy surfaces and reaction dynamics / The partnership between electronic structure calculations and experiments in the study of reactive intermediates